A molecular "screw-clamp": accelerating click reactions in miniemulsions.
نویسندگان
چکیده
The interface as a "screw clamp": the copper-free 1,3-dipolar azide-alkyne cycloaddition at the interface of nanodroplets in miniemulsions was studied in detail by NMR spectroscopic methods. The reaction at the oil-water interface proved to exhibit higher rate constants, increased molecular weights and high regioregularity compared to the reaction in solution.
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عنوان ژورنال:
- Chemical communications
دوره 50 72 شماره
صفحات -
تاریخ انتشار 2014